Enthalpy-entropy compensation in the denaturation of proteins of bovine masseter and cutaneous trunci.

Abstract

Thermal properties of muscles are of great interest in meat science. A recent article (Vaskoska et al., 2021) examines the thermal denaturation of proteins in bovine muscles, masseter and cutaneous trunci, by measuring the enthalpy and melting temperature of the denaturation. In the present article, we report the numerical values of entropy in the denaturation of proteins. Furthermore, we describe a characteristic phenomenon, enthalpy-entropy compensation in the denaturation of bovine proteins. To our knowledge, this is the first observation of the compensation in situ condition. The analysis shown in this paper may develop a new approach in meat science by introducing a new parameter, entropy, that is rarely reported in relation to differential scanning calorimetry results in this field of research. Therefore, it may enhance our understanding of the thermal properties of meat from a physical chemistry perspective.